{"id":1762,"date":"2023-01-11T11:03:29","date_gmt":"2023-01-11T09:03:29","guid":{"rendered":"https:\/\/desarrollo.idealcofund-project.eu\/phd\/?page_id=1762"},"modified":"2023-03-15T19:39:47","modified_gmt":"2023-03-15T17:39:47","slug":"structure-property-function-relationships-in-metal-organic-frameworks-for-energy-harvesting","status":"publish","type":"page","link":"https:\/\/idealcofund-project.eu\/phd\/phd-projects\/structure-property-function-relationships-in-metal-organic-frameworks-for-energy-harvesting\/","title":{"rendered":"Structure-property-function relationships in Metal Organic Frameworks for Energy Harvesting"},"content":{"rendered":"<p>[et_pb_section fb_built=&#8221;1&#8243; _builder_version=&#8221;4.9.4&#8243; _module_preset=&#8221;default&#8221; background_enable_image=&#8221;off&#8221; custom_padding=&#8221;2px||12px|||&#8221; global_module=&#8221;509&#8243; saved_tabs=&#8221;all&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row use_custom_gutter=&#8221;on&#8221; gutter_width=&#8221;1&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; width=&#8221;100%&#8221; max_width=&#8221;100%&#8221; custom_padding=&#8221;4px|||||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_divider divider_weight=&#8221;60px&#8221; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; width=&#8221;100%&#8221; max_width=&#8221;100%&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_divider][\/et_pb_column][\/et_pb_row][et_pb_row _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][lwp_divi_breadcrumbs home_text=&#8221;Inicio&#8221; use_before_icon=&#8221;off&#8221; link_color=&#8221;#89B7CA&#8221; current_text_color=&#8221;#001733&#8243; _builder_version=&#8221;4.18.0&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;||0px|||&#8221; global_colors_info=&#8221;{}&#8221;][\/lwp_divi_breadcrumbs][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;0px||5px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_row _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;||6px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text _builder_version=&#8221;4.18.0&#8243; _module_preset=&#8221;default&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h1>Structure-property-function relationships in Metal Organic Frameworks for Energy Harvesting<\/h1>\n<p>[\/et_pb_text][et_pb_text _builder_version=&#8221;4.18.0&#8243; _module_preset=&#8221;default&#8221; custom_margin=&#8221;||29px|||&#8221; locked=&#8221;off&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h2><strong>RESEARCH PROGRAMMES<\/strong><\/h2>\n<p>P1: Nanotechnology for energy harvesting<\/p>\n<p>P5: Ultrafast phenomena at the nanoscale<\/p>\n<p>[\/et_pb_text][et_pb_text _builder_version=&#8221;4.18.0&#8243; _module_preset=&#8221;default&#8221; custom_margin=&#8221;||0px||false|false&#8221; custom_padding=&#8221;0px||||false|false&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h2><strong>PhD PROJECT DESCRIPTION<\/strong><\/h2>\n<p style=\"text-align: justify;\">The future of electrically conducting materials is moving apart from the current design-limited metal-oxide semiconductors technology. In this perspective, three-dimensional metal-organic frameworks (MOFs) containing transition metals have been proposed as an elegant synthetic strategy to achieve novel electrically conducting materials. Although this research is still in its infancy, mainly due to the low conductivity nature of these materials, some strategies exist to critically improve electron transport allowing one to reach conductivities comparable to that of graphene. This recent discovery of electrically conductive MOFs has hence opened broad areas of potential applications of MOFs in optoelectronics and gas sensing.<\/p>\n<p style=\"text-align: justify;\">This project is devoted to the electrical characterization study of novel switchable 3D MOF by means of which new functional molecule-based materials. These unprecedented architectures will be based on a coordination switchable compound formed by: i) a Spin CrossOver (SCO) metal centre, providing great sensitivity through signal transduction, and ii) a modified organic ligand, providing high electron conducting transport through the network. Excitingly, these structures will be capable of showing at room temperature an amplified, reversible, and easily detectable signal.<\/p>\n<p style=\"text-align: justify;\">To effectively tackle these challenges, the work is structured in the following specific <strong>research objectives:<\/strong><\/p>\n<ul style=\"text-align: justify;\">\n<li>Macroscopic scale design, synthesis, structural and physico-chemical characterization of novel SCO-based 3D MOF materials will be developed. For the first time, the highly sensitive properties of SCO components will be combined with highly electrical conductivity 3D networks. The synthesis of 3\u2212D MOF family based on the {Fe2(bdp)3} family being the bdp, 1,4-benzenedipyrazolate is of great interest because: i) the Fe2(bdp)3 based-materials form triangular highly stable structures with high porosity; ii) a polymorph of this framework has been reported by Long and Dinca\u0306 et al. to provide the highest conductance ever reported in MOFs and iii) remarkably the coordination sphere surrounding the iron metal centre has the adequate ligand field to show the switchable spin crossover behavior as reported in similar structures.<\/li>\n<li>For analyzing carrier dynamics, the main tool that will be employed will be time-resolved Terahertz spectroscopy, a tool that allows the determination of the time resolved (photo)conductivity of a sample in a contactless fashion and on ultrafast timescales. This tool will be eventually complemented by conductivity contact methods as 4-probe and Quantum Hall effect. Secondment options at the Max Planck institute for polymer research in Mainz (Dept. of Molecular Spectroscopy \u2013 Prof. Mischa Bonn) and Technical University of Dresden (Prof. Xinliang Feng) are viable for deepening into mastering ultrafast spectroscopy and synthesis respectively.<\/li>\n<li>Maximizing the impact of this project through disseminating and communicating about the project and its results to the different target audiences and through promoting the exploitation of the most relevant results.<\/li>\n<\/ul>\n<p style=\"text-align: justify;\">The selected candidate will benefit from an exciting line of research within a high profile international collaboration; and being exposed to different scientific environments and world-class facilities.<\/p>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][et_pb_row _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;||6px|||&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_column type=&#8221;4_4&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221;][et_pb_text disabled_on=&#8221;off|off|off&#8221; _builder_version=&#8221;4.18.0&#8243; _module_preset=&#8221;default&#8221; custom_margin=&#8221;||29px|||&#8221; custom_padding=&#8221;0px|||||&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h2 style=\"text-align: left;\"><strong>APPLICANT&#8217;S REQUIREMENTS<\/strong><\/h2>\n<p style=\"text-align: justify;\">The candidate should have background in Physical-Chemistry, Material Science or in a closely related field of science. An ideal candidate will have research interests aligned with: charge carrier dynamics, charge transport, and coordination polymers called metal-organic frameworks. A general chemistry background is highly appreciated mainly in coordination chemistry to allow the student to achieve the synthetic goal of this project. Practical skills on electrical characterization (optical and magneto-electrical) will be an advantage for the development of the project. Furthermore, the ability to work on an interdisciplinary topic and international environment, analytical but creative thinking and effective communication skills are also of importance.<\/p>\n<p>[\/et_pb_text][et_pb_text _builder_version=&#8221;4.18.0&#8243; _module_preset=&#8221;default&#8221; custom_margin=&#8221;||29px||false|false&#8221; custom_padding=&#8221;0px||||false|false&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h2><strong>RESEARCH GROUP DESCRIPTION<\/strong><\/h2>\n<p style=\"text-align: justify;\">The project will be conducted at IMDEA Nanoscience (Madrid, Spain), a Severo Ochoa center of excellence, in the groups of Enrique C\u00e1novas and Jos\u00e9 Sanchez Costa.<\/p>\n<p style=\"text-align: justify;\">Dr. C\u00e1novas\u00b4 group (Nanostructured Photovoltaics) is focused on studying carrier dynamics and charge transport in semiconductors and their nano-structures. The group is composed by 3PDs, 4PhDs and 1 Technician.<\/p>\n<p style=\"text-align: justify;\">Dr. Jose Sanchez Costa (Switchable Nanomaterials) is developing multifunctional switchable coordination porous materials at different scale of matter (from bulk crystals to the nanosize). The group is actually composed by 3 PDs and 2 PhD students.<\/p>\n<p>[\/et_pb_text][et_pb_text _builder_version=&#8221;4.18.0&#8243; _module_preset=&#8221;default&#8221; custom_margin=&#8221;||29px||false|false&#8221; custom_padding=&#8221;0px||||false|false&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h2><strong>RESEARCH SUPERVISOR<\/strong><\/h2>\n<p>Prof. Enrique C\u00e1novas D\u00edaz<br \/><a href=\"mailto:enrique.canovas@imdea.org\">enrique.canovas@imdea.org<\/a><\/p>\n<p>Research Group website:<a href=\"https:\/\/ecanovas6.wixsite.com\/nanopv\">https:\/\/ecanovas6.wixsite.com\/nanopv<\/a><\/p>\n<p>Other websites:<\/p>\n<p><a href=\"https:\/\/www.mpip-mainz.mpg.de\/en\/bonn\">https:\/\/www.mpip-mainz.mpg.de\/en\/bonn<\/a><br \/><a href=\"https:\/\/tu-dresden.de\/mn\/chemie\/mc\/mc2\/die-professur\">https:\/\/tu-dresden.de\/mn\/chemie\/mc\/mc2\/die-professur<\/a><a href=\"https:\/\/www.mpip-mainz.mpg.de\/en\/bonn\"><\/a><\/p>\n<p>[\/et_pb_text][et_pb_code _builder_version=&#8221;4.18.0&#8243; _module_preset=&#8221;default&#8221; global_colors_info=&#8221;{}&#8221; locked=&#8221;off&#8221;]<a href=\"https:\/\/twitter.com\/share?ref_src=twsrc%5Etfw\" class=\"twitter-share-button\" data-show-count=\"false\">Tweet<\/a><script async src=\"https:\/\/platform.twitter.com\/widgets.js\" charset=\"utf-8\"><\/script><!-- [et_pb_line_break_holder] -->[\/et_pb_code][et_pb_text disabled_on=&#8221;on|on|on&#8221; _builder_version=&#8221;4.18.0&#8243; _module_preset=&#8221;default&#8221; header_3_text_color=&#8221;#5D5A5A&#8221; custom_margin=&#8221;||29px||false|false&#8221; custom_padding=&#8221;0px||||false|false&#8221; disabled=&#8221;on&#8221; global_colors_info=&#8221;{}&#8221;]<\/p>\n<h2><strong>ETHICS SELF-ASSESSMENT<\/strong><\/h2>\n<h3><\/h3>\n<h3>1. Human Embryonic Stem Cells and Human Embryos<\/h3>\n<table border=\"1\" style=\"width: 100%; border-collapse: collapse; float: left;\">\n<tbody>\n<tr>\n<td style=\"width: 125%;\">Does this activity involve Human Embryonic Stem Cells (hESCs)?<\/td>\n<td style=\"width: 27.4194%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 125%;\">Does this activity involve the use of human embryos?<\/td>\n<td style=\"width: 27.4194%;\">No<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3><\/h3>\n<h3><\/h3>\n<h3><\/h3>\n<h3>2. Humans<\/h3>\n<table border=\"1\" style=\"border-collapse: collapse; width: 100%;\">\n<tbody>\n<tr>\n<td style=\"width: 96.1291%;\">Does this activity involve human participants?<\/td>\n<td style=\"width: 3.87092%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 96.1291%;\">Does this activity involve interventions (physical also including imaging technology, behavioural treatments, etc.) on the study participants?<\/td>\n<td style=\"width: 3.87092%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 96.1291%;\">Does this activity involve conducting a clinical study as defined by the Clinical Trial Regulation (EU 536\/2014)? (using pharmaceuticals, biologicals, radiopharmaceuticals, or advanced therapy medicinal products)<\/td>\n<td style=\"width: 3.87092%;\">No<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>3. Human cells\/Tissues<\/h3>\n<table border=\"1\" style=\"border-collapse: collapse; width: 100%;\">\n<tbody>\n<tr>\n<td style=\"width: 96.7742%;\">Does this activity involve the use of human cells or tissues?<\/td>\n<td style=\"width: 3.22581%;\">No<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>4. Personal Data<\/h3>\n<table border=\"1\" style=\"border-collapse: collapse; width: 100%;\">\n<tbody>\n<tr>\n<td style=\"width: 98.0754%;\">Does this activity involve processing of personal data?<\/td>\n<td style=\"width: 6.14888%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 98.0754%;\">Does this activity involve further processing of previously collected personal data (including use of preexisting data sets or sources, merging existing data sets)?<\/td>\n<td style=\"width: 6.14888%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 98.0754%;\">Is it planned to export personal data from the EU to non-EU countries? Specify the type of personal data and countries involved<\/td>\n<td style=\"width: 6.14888%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 98.0754%;\">Is it planned to import personal data from non-EU countries into the EU or from a non-EU country to another non-EU country? Specify the type of personal data and countries involved<\/td>\n<td style=\"width: 6.14888%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 98.0754%;\">Does this activity involve the processing of personal data related to criminal convictions or offences?<\/td>\n<td style=\"width: 6.14888%;\">No<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>5. Animals<\/h3>\n<table border=\"1\" style=\"border-collapse: collapse; width: 100%;\">\n<tbody>\n<tr>\n<td style=\"width: 95.4839%;\">Does this activity involve animals?<\/td>\n<td style=\"width: 4.51613%;\">No<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>6. Non-EU Countries<\/h3>\n<table border=\"1\" style=\"border-collapse: collapse; width: 100%;\">\n<tbody>\n<tr>\n<td style=\"width: 120.729%;\">Will some of the activities be carried out in non-EU countries?<\/td>\n<td style=\"width: 3.23625%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 120.729%;\">In case non-EU countries are involved, do the activities undertaken in these countries raise potential ethics issues?<\/td>\n<td style=\"width: 3.23625%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 120.729%;\">It is planned to use local resources (e.g. animal and\/or human tissue samples, genetic material, live animals, human remains, materials of historical value, endangered fauna or flora samples, etc.)?<\/td>\n<td style=\"width: 3.23625%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 120.729%;\">Is it planned to import any material (other than data) from non-EU countries into the EU or from a non-EU country to another non-EU country?<\/td>\n<td style=\"width: 3.23625%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 120.729%;\">Is it planned to export any material (other than data) from the EU to non-EU countries?<\/td>\n<td style=\"width: 3.23625%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 120.729%;\">Does this activity involve low and\/or lower middle income countries?<\/td>\n<td style=\"width: 3.23625%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 120.729%;\">Could the situation in the country put the individuals taking part in the activity at risk?<\/td>\n<td style=\"width: 3.23625%;\">No<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>7. Environment, Health and Safety<\/h3>\n<table border=\"1\" style=\"border-collapse: collapse; width: 100%;\">\n<tbody>\n<tr>\n<td style=\"width: 97.4194%;\">Does this activity involve the use of substances or processes that may cause harm to the environment, to animals or plants.(during the implementation of the activity or further to the use of the results, as a possible impact) ?<\/td>\n<td style=\"width: 3.22581%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 97.4194%;\">Does this activity deal with endangered fauna and\/or flora \/ protected areas?<\/td>\n<td style=\"width: 3.22581%;\">No<\/td>\n<\/tr>\n<tr>\n<td style=\"width: 97.4194%;\">Does this activity involve the use of substances or processes that may cause harm to humans, including those performing the activity.(during the implementation of the activity or further to the use of the results, as a possible impact) ?<\/td>\n<td style=\"width: 3.22581%;\">No<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>8. Artificial Intelligence<\/h3>\n<table border=\"1\" style=\"border-collapse: collapse; width: 100%;\">\n<tbody>\n<tr>\n<td style=\"width: 95.8065%;\">Does this activity involve the development, deployment and\/or use of Artificial Intelligence?<\/td>\n<td style=\"width: 4.19359%;\">No<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>&nbsp;<\/p>\n<table border=\"1\" style=\"border-collapse: collapse; width: 100%;\">\n<tbody>\n<tr>\n<td style=\"width: 98.3871%;\">Are there any other ethics issues that should be taken into consideration?<\/td>\n<td style=\"width: 3.22581%;\">No<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>&nbsp;<\/p>\n<p>[\/et_pb_text][\/et_pb_column][\/et_pb_row][\/et_pb_section][et_pb_section fb_built=&#8221;1&#8243; _builder_version=&#8221;4.16&#8243; _module_preset=&#8221;default&#8221; custom_padding=&#8221;0px|||||&#8221; global_colors_info=&#8221;{}&#8221;][\/et_pb_section]<\/p>\n","protected":false},"excerpt":{"rendered":"<p><div class=\"et_pb_module lwp_divi_breadcrumbs lwp_divi_breadcrumbs_0\">\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t\n\t\t\t\t<div class=\"et_pb_module_inner\">\n\t\t\t\t\t<div class=\"lwp-breadcrumbs\"> <span class=\"before\"><\/span> <span vocab=\"https:\/\/schema.org\/\" typeof=\"BreadcrumbList\"><span property=\"itemListElement\" typeof=\"ListItem\"><a property=\"item\" typeof=\"WebPage\" href=\"https:\/\/idealcofund-project.eu\/phd\/\" class=\"home\"><span property=\"name\">Inicio<\/span><\/a><meta property=\"position\" content=\"1\"><\/span> <span class=\"separator et-pb-icon\">&amp;#x39;<\/span> <\/span><\/div>\n\t\t\t\t<\/div>\n\t\t\t<\/div>Structure-property-function relationships in Metal Organic Frameworks for Energy HarvestingRESEARCH PROGRAMMES P1: Nanotechnology for energy harvesting P5: Ultrafast phenomena at the nanoscalePhD PROJECT DESCRIPTION The future of electrically conducting materials is moving apart from the current design-limited metal-oxide semiconductors technology. In this perspective, three-dimensional metal-organic frameworks (MOFs) containing [&hellip;]<\/p>\n","protected":false},"author":156,"featured_media":0,"parent":625,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"_et_pb_use_builder":"on","_et_pb_old_content":"","_et_gb_content_width":"","inline_featured_image":false,"footnotes":""},"class_list":["post-1762","page","type-page","status-publish","hentry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v23.0 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Structure-property-function relationships in Metal Organic Frameworks for Energy Harvesting - IDEAL PhD Cofund<\/title>\n<meta name=\"robots\" content=\"noindex, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Structure-property-function relationships in Metal Organic Frameworks for Energy Harvesting - IDEAL PhD Cofund\" \/>\n<meta property=\"og:description\" content=\"Structure-property-function relationships in Metal Organic Frameworks for Energy HarvestingRESEARCH PROGRAMMES P1: Nanotechnology for energy harvesting P5: Ultrafast phenomena at the nanoscalePhD PROJECT DESCRIPTION The future of electrically conducting materials is moving apart from the current design-limited metal-oxide semiconductors technology. 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